Orthometalated N-(Benzophenoxazine)-o-aminophenol: Phenolato versus Phenoxyl States
نویسندگان
چکیده
منابع مشابه
Tris[2-(propyliminomethyl)phenolato-κ2 N,O]cobalt(III)
The title compound, [Co(C(10)H(12)NO)(3)], was synthesized from cobalt(III) fluoride and 2-(propyl-imino-meth-yl)phenol in refluxing methanol. The Co(III) ion is hexa-coordinated by three N and three O atoms from three bidentate Schiff base ligands in an octa-hedral geometry.
متن کاملTris[2-(propyliminomethyl)phenolato-κ2 N,O]iron(III)
The title compound, [Fe(C(10)H(12)NO)(3)], is isostructural with its Co(III)-containing analogue. The Fe(III) cation is chelated by three Schiff base ligands via three N and three O atoms, and exhibits a slightly distorted octa-hedral geometry. The longest Fe-O and Fe-N bonds lie trans to each other and may be regarded as axial bonds, while the equatorial plane contains two mutually trans O and...
متن کاملBis[2-(1-iminoethyl)phenolato-κ2 N,O]nickel(II)
There are one and a half independent mol-ecules in the asymmetric unit of the title compound, [Ni(C(8)H(8)NO)(2)], one of which is situated on an inversion center. In both mol-ecules, the Ni(II) ion is coordinated by two O and two N atoms from two Schiff base ligands in an approximate square-planar geometry. Inter-molecular N-H⋯O hydrogen bonds link three mol-ecules into centrosymmetric trimer....
متن کاملTris[2-(benzyliminomethyl)phenolato-κ2 N,O]iron(III)
In the title compound, [Fe(C(14)H(12)NO)(3)], the Fe(III) atom has a slightly distorted octa-hedral geometry and is coordinated by three Schiff base ligands, viz. 2-(benzyl-imino-methyl)-phenolate. The crystal structure is stabilized by intra-molecular C-H⋯O and C-H⋯N hydrogen bonds.
متن کامل(Acetylacetonato-κ2 O,O′)(2-bromo-4-chloro-6-{[2-(dimethylamino)ethylimino]methyl}phenolato-κ3 N,N′,O)oxidovanadium(IV)
The V(IV) atom in the title complex, [V(C(11)H(13)BrClN(2)O)(C(5)H(7)O(2))O], is six-coordinated by one phenolate O, one imino N and one amino N atom of the tridentate anionic Schiff base ligand, by one oxide O atom, and by two O atoms of an acetyl-acetonate anion, forming a distorted cis-VN(2)O(4) octa-hedral coordination geometry. The deviation of the V atom from the plane defined by the thre...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: ACS Omega
سال: 2018
ISSN: 2470-1343,2470-1343
DOI: 10.1021/acsomega.8b01983